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Issue 4, 2013
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On the incidence of non-covalent intramolecular interligand interactions on the conformation of carbene complexes: a case study

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Abstract

The prevalence of a counterintuitive carbene conformation in a series of piano-stool Mn(I) alkylalkoxycarbene complexes was rationalized by means of DFT calculations and high-resolution XRD analysis in terms of stabilizing non-covalent C–H⋯C[triple bond, length as m-dash]O interligand interactions.

Graphical abstract: On the incidence of non-covalent intramolecular interligand interactions on the conformation of carbene complexes: a case study

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Publication details

The article was received on 24 Oct 2012, accepted on 22 Nov 2012 and first published on 22 Nov 2012


Article type: Communication
DOI: 10.1039/C2DT32554C
Dalton Trans., 2013,42, 898-901

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    On the incidence of non-covalent intramolecular interligand interactions on the conformation of carbene complexes: a case study

    N. Lugan, I. Fernández, R. Brousses, D. A. Valyaev, G. Lavigne and N. A. Ustynyuk, Dalton Trans., 2013, 42, 898
    DOI: 10.1039/C2DT32554C

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