Issue 4, 2013
From the journal:

Dalton Transactions

On the incidence of non-covalent intramolecular interligand interactions on the conformation of carbene complexes: a case study†

Noël Lugan,*ab   Israel Fernández,*c   Rémy Brousses,ab   Dmitry A. Valyaev,abd   Guy Lavigneab  and  Nikolai A. Ustynyukd  

* Corresponding authors

a Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, BP 44099, 31077 Toulouse Cedex 4, France
E-mail: noel.lugan@lcc-toulouse.fr
Fax: +33 5 61 55 30 03
Tel: +33 5 61 33 31 71

b Université de Toulouse, UPS, INPT, 31077 Toulouse Cedex 4, France

c Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, 28040 Madrid, Spain
E-mail: israel@quim.ucm.es

d A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov str., GSP-1, B-334, 119991 Moscow, Russia

Abstract

The prevalence of a counterintuitive carbene conformation in a series of piano-stool Mn(I) alkylalkoxycarbene complexes was rationalized by means of DFT calculations and high-resolution XRD analysis in terms of stabilizing non-covalent C–H⋯C[triple bond, length as m-dash]O interligand interactions.

Graphical abstract: On the incidence of non-covalent intramolecular interligand interactions on the conformation of carbene complexes: a case study

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Article information

DOI
https://doi.org/10.1039/C2DT32554C
Article type
Communication
Submitted
24 Oct 2012
Accepted
22 Nov 2012
First published
22 Nov 2012

Dalton Trans., 2013,42, 898-901

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On the incidence of non-covalent intramolecular interligand interactions on the conformation of carbene complexes: a case study

N. Lugan, I. Fernández, R. Brousses, D. A. Valyaev, G. Lavigne and N. A. Ustynyuk, Dalton Trans., 2013, 42, 898 DOI: 10.1039/C2DT32554C

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