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Issue 2, 2013
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Hydrogenation of imines catalysed by ruthenium(ii) complexes based on lutidine-derived CNC pincer ligands

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Abstract

The preparation of new Ru(II) complexes incorporating fac-coordinated lutidine-derived CNC ligands is reported. These derivatives are selectively deprotonated by tBuOK at one of the methylene arms of the pincer, leading to catalytically active species in the hydrogenation of imines.

Graphical abstract: Hydrogenation of imines catalysed by ruthenium(ii) complexes based on lutidine-derived CNC pincer ligands

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Article information


Submitted
20 Aug 2012
Accepted
26 Sep 2012
First published
03 Oct 2012

Dalton Trans., 2013,42, 351-354
Article type
Communication

Hydrogenation of imines catalysed by ruthenium(II) complexes based on lutidine-derived CNC pincer ligands

M. Hernández-Juárez, M. Vaquero, E. Álvarez, V. Salazar and A. Suárez, Dalton Trans., 2013, 42, 351
DOI: 10.1039/C2DT31907A

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