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Issue 6, 2013
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High energy resolution fluorescence detectionXANES – an in situ method to study the interaction of adsorbed molecules with metal catalysts in the liquid phase

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Abstract

The change in the Pt electronic structure following the adsorption of an α,β-unsaturated aldehyde and ketone was followed by in situ HERFD-XANES in the liquid phase. The resulting shift in the Pt Fermi energy is in good agreement with the molecule adsorption energy trends calculated by DFT and provides insight into the reaction selectivity.

Graphical abstract: High energy resolution fluorescence detection XANES – an in situ method to study the interaction of adsorbed molecules with metal catalysts in the liquid phase

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Article information


Submitted
11 Jan 2013
Accepted
08 Apr 2013
First published
09 Apr 2013

Catal. Sci. Technol., 2013,3, 1497-1500
Article type
Communication

High energy resolution fluorescence detection XANES – an in situ method to study the interaction of adsorbed molecules with metal catalysts in the liquid phase

H. G. Manyar, R. Morgan, K. Morgan, B. Yang, P. Hu, J. Szlachetko, J. Sá and C. Hardacre, Catal. Sci. Technol., 2013, 3, 1497
DOI: 10.1039/C3CY00031A

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