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Issue 3, 2013
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Secondary phosphine oxides as pre-ligands for nanoparticle stabilization

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Abstract

The synthesis of ruthenium nanoparticles (RuNPs) using secondary phosphine oxides (SPOs) as ligands is reported. These easily accessible ligands allow the formation of small nanoparticles in the size range of 1–2 nm which display a high efficiency for hydrogenation of aromatics with TOFs up to 2700 mol h−1.

Graphical abstract: Secondary phosphine oxides as pre-ligands for nanoparticle stabilization

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Publication details

The article was received on 04 Oct 2012, accepted on 21 Nov 2012 and first published on 12 Dec 2012


Article type: Paper
DOI: 10.1039/C2CY20683H
Catal. Sci. Technol., 2013,3, 595-599

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    Secondary phosphine oxides as pre-ligands for nanoparticle stabilization

    E. Rafter, T. Gutmann, F. Löw, G. Buntkowsky, K. Philippot, B. Chaudret and P. W. N. M. van Leeuwen, Catal. Sci. Technol., 2013, 3, 595
    DOI: 10.1039/C2CY20683H

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