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Issue 3, 2013
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Alternative approaches for the aqueous–organic biphasic hydroformylation of higher alkenes

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Abstract

The biphasic hydroformylation of linear alkenes using the Rh–TPPTS catalyst system is one of the cornerstones of aqueous biphasic catalysis, but due to mass-transfer limitations its application is restricted to short alkenes. This perspective provides an overview of various alternative approaches which have been developed to extend the aqueous biphasic methodology to the hydroformylation of higher alkenes.

Graphical abstract: Alternative approaches for the aqueous–organic biphasic hydroformylation of higher alkenes

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Article information


Submitted
31 Jul 2012
Accepted
10 Sep 2012
First published
14 Sep 2012

Catal. Sci. Technol., 2013,3, 541-551
Article type
Perspective

Alternative approaches for the aqueous–organic biphasic hydroformylation of higher alkenes

L. Obrecht, P. C. J. Kamer and W. Laan, Catal. Sci. Technol., 2013, 3, 541
DOI: 10.1039/C2CY20538F

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