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Issue 3, 2013
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Alternative approaches for the aqueous–organic biphasic hydroformylation of higher alkenes

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Abstract

The biphasic hydroformylation of linear alkenes using the Rh–TPPTS catalyst system is one of the cornerstones of aqueous biphasic catalysis, but due to mass-transfer limitations its application is restricted to short alkenes. This perspective provides an overview of various alternative approaches which have been developed to extend the aqueous biphasic methodology to the hydroformylation of higher alkenes.

Graphical abstract: Alternative approaches for the aqueous–organic biphasic hydroformylation of higher alkenes

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Publication details

The article was received on 31 Jul 2012, accepted on 10 Sep 2012 and first published on 14 Sep 2012


Article type: Perspective
DOI: 10.1039/C2CY20538F
Catal. Sci. Technol., 2013,3, 541-551

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    Alternative approaches for the aqueous–organic biphasic hydroformylation of higher alkenes

    L. Obrecht, P. C. J. Kamer and W. Laan, Catal. Sci. Technol., 2013, 3, 541
    DOI: 10.1039/C2CY20538F

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