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Issue 13, 2013
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Molecule–electrode interfaces in molecular electronic devices

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Understanding charge transport of single molecules or a small collection of molecules sandwiched between electrodes is of fundamental importance for molecular electronics. This requires the fabrication of reliable devices, which depend on several factors including the testbed architectures used, the molecule number and defect density being tested, and the nature of the molecule–electrode interface. On the basis of significant progresses achieved in both experiments and theory over the past decade, in this tutorial review, we focus on new insights into the influence of the nature of the molecule–electrode interface, the most critical issue hindering the development of reliable devices, on the conducting properties of molecules. We summarize the strategies developed for controlling the interfacial properties and how the coupling strength between the molecules and the electrodes modulates the device properties. These analyses should be valuable for deeply understanding the relationship between the contact interface and the charge transport mechanism, which is of crucial importance for the development of molecular electronics, organic electronics, nanoelectronics, and other interface-related optoelectronic devices.

Graphical abstract: Molecule–electrode interfaces in molecular electronic devices

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Publication details

The article was received on 27 Dec 2012 and first published on 09 Apr 2013

Article type: Tutorial Review
DOI: 10.1039/C3CS35527F
Chem. Soc. Rev., 2013,42, 5642-5660

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    Molecule–electrode interfaces in molecular electronic devices

    C. Jia and X. Guo, Chem. Soc. Rev., 2013, 42, 5642
    DOI: 10.1039/C3CS35527F

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