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Issue 8, 2013
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Nano-magnetite (Fe3O4) as a support for recyclable catalysts in the development of sustainable methodologies

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Abstract

Surface functionalization of nano-magnetic nanoparticles is a well-designed way to bridge the gap between heterogeneous and homogeneous catalysis. The introduction of magnetic nanoparticles (MNPs) in a variety of solid matrices allows the combination of well-known procedures for catalyst heterogenization with techniques for magnetic separation. Magnetite is a well-known material, also known as ferrite (Fe3O4), and can be used as a versatile support for functionalization of metals, organocatalysts, N-heterocyclic carbenes, and chiral catalysts. It is used as a support for important homogeneous catalytically active metals such as Pd, Pt, Cu, Ni, Co, Ir, etc. to obtain stable and magnetically recyclable heterogeneous catalysts. Homogeneous organocatalysts can be successfully decorated with linkers/ligands on the surface of magnetite or alternatively the organocatalysts can be directly immobilized on the surface of magnetite. The functionalized magnetically retrievable catalysts or nanocatalysts that are increasingly being used in catalysis, green chemistry and pharmaceutically significant reactions are summarized in this review.

Graphical abstract: Nano-magnetite (Fe3O4) as a support for recyclable catalysts in the development of sustainable methodologies

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Publication details

The article was received on 26 Nov 2012 and first published on 18 Feb 2013


Article type: Review Article
DOI: 10.1039/C3CS35480F
Chem. Soc. Rev., 2013,42, 3371-3393

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    Nano-magnetite (Fe3O4) as a support for recyclable catalysts in the development of sustainable methodologies

    M. B. Gawande, P. S. Branco and R. S. Varma, Chem. Soc. Rev., 2013, 42, 3371
    DOI: 10.1039/C3CS35480F

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