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Issue 11, 2013
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Chemically-synthesised, atomically-precise gold clusters deposited and activated on titania

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Abstract

Synchrotron XPS was used to investigate a series of chemically-synthesised, atomically-precise gold clusters Aun(PPh3)y (n = 8, 9, 11 and 101, with y depending on cluster size) immobilized on titania nanoparticles. The gold clusters were washed with toluene at 100 °C or calcined at 200 °C to remove the organic ligand. From the position of the Au 4f7/2 peak it is concluded that cluster size is not altered through the deposition. From the analysis of the phosphorous spectra, it can be concluded that the applied heat treatment removes the organic ligands. Washing and calcination leads to partial oxidation and partial agglomeration of the clusters. Oxidation of the clusters is most likely due to the interaction of the cluster core with the oxygen of the titania surface after removal of ligands. The position of the Au 4f7/2 peak indicates that the size of the agglomerated clusters is still smaller than that of Au101.

Graphical abstract: Chemically-synthesised, atomically-precise gold clusters deposited and activated on titania

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Article information


Submitted
11 Nov 2012
Accepted
16 Jan 2013
First published
17 Jan 2013

This article is Open Access

Phys. Chem. Chem. Phys., 2013,15, 3917-3929
Article type
Paper

Chemically-synthesised, atomically-precise gold clusters deposited and activated on titania

D. P. Anderson, J. F. Alvino, A. Gentleman, H. A. Qahtani, L. Thomsen, M. I. J. Polson, G. F. Metha, V. B. Golovko and G. G. Andersson, Phys. Chem. Chem. Phys., 2013, 15, 3917
DOI: 10.1039/C3CP44005B

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