Encapsulation of polyoxometalates within layered metal–organic frameworks with topological and pore control†
Organic links of varied structure metrics and functionalities connect with Cu2(COO)4 clusters to afford layered metal–organic frameworks. Through topological and pore control, polyoxometalates could be synthetically encapsulated within the cavities. The templating effects of polyoxometalates and specific link functionalizations provide two strategies for controllably incorporating these active species into frameworks.
- This article is part of the themed collection: Structural Design of Coordination Polymers