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Issue 45, 2013
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A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm†

Yabing He,*a   Hiroyasu Furukawa,b   Chuande Wu,c   Michael O'Keeffed  and  Banglin Chen*e  
Author affiliations

* Corresponding authors

a College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China
E-mail: heyabing@gmail.com

b Department of Chemistry, University of California, Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

c Department of Chemistry, Zhejiang University, Hangzhou 310027, China

d Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287, USA

e Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA
E-mail: banglin.chen@utsa.edu
Fax: +1-210-458-7428

Abstract

Solvothermal reaction of a dendritic hexacarboxylic acid with Tb(NO3)3·6H2O afforded a mesoporous lanthanide–organic framework (UTSA-61) whose single-crystal X-ray structure was characterized to have octahedral cages of 2.4 nm in diameter. This mesoporous MOF not only exhibits novel hey topology, but also maintains permanent porosity as shown in its N2, H2, CO2 and CH4 gas sorption isotherms.

Graphical abstract: A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

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Article information

https://doi.org/10.1039/C3CE41062E
Submitted
08 Jun 2013
Accepted
29 Jul 2013
First published
31 Jul 2013
CrystEngComm, 2013,15, 9328-9331
Article type
Communication
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A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

Y. He, H. Furukawa, C. Wu, M. O'Keeffe and B. Chen, CrystEngComm, 2013, 15, 9328
DOI: 10.1039/C3CE41062E

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