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Issue 93, 2013
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Room temperature switching of a neutral molecular iron(ii) complex

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Abstract

Abrupt room temperature switching (Tc = 295 K with a 5 K hysteresis) was achieved in a neutral FeII complex based on a 2-(1H-pyrazol-1-yl)-6-(1H-tetrazol-5-yl)pyridine ligand. Structural characterization and spin crossover study (via SQUID magnetometry, photoexcitation and X-ray absorption spectroscopy) in the solid state are described.

Graphical abstract: Room temperature switching of a neutral molecular iron(ii) complex

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Article information


Submitted
29 Aug 2013
Accepted
02 Oct 2013
First published
03 Oct 2013

Chem. Commun., 2013,49, 10986-10988
Article type
Communication

Room temperature switching of a neutral molecular iron(II) complex

B. Schäfer, C. Rajnák, I. Šalitroš, O. Fuhr, D. Klar, C. Schmitz-Antoniak, E. Weschke, H. Wende and M. Ruben, Chem. Commun., 2013, 49, 10986
DOI: 10.1039/C3CC46624H

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