Issue 87, 2013
From the journal:

Chemical Communications

Copper-catalyzed direct oxysulfonylation of alkenes with dioxygen and sulfonylhydrazides leading to β-ketosulfones†

Wei Wei,ab   Chunli Liu,ab   Daoshan Yang,ab   Jiangwei Wen,ab   Jinmao You,abc   Yourui Suoc  and  Hua Wang*ab  

* Corresponding authors

a The Key Laboratory of Life-Organic Analysis, Qufu Normal University, Qufu 273165, China
E-mail: huawang_qfnu@126.com

b Key Laboratory of Pharmaceutical Intermediates and Analysis of Natural Medicine, Qufu Normal University, Qufu 273165, China

c Northwest Institute of Plateau Biology, Chinese Academy of Sciences, Xining 810001, PR China

Abstract

The first copper-catalyzed oxysulfonylation reaction of alkenes with dioxygen and sulfonylhydrazides for the construction of β-ketosulfones has been developed under mild conditions without any ligand or additive.

Graphical abstract: Copper-catalyzed direct oxysulfonylation of alkenes with dioxygen and sulfonylhydrazides leading to β-ketosulfones

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Article information

DOI
https://doi.org/10.1039/C3CC45803B
Article type
Communication
Submitted
30 Jul 2013
Accepted
10 Sep 2013
First published
10 Sep 2013

Chem. Commun., 2013,49, 10239-10241

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Copper-catalyzed direct oxysulfonylation of alkenes with dioxygen and sulfonylhydrazides leading to β-ketosulfones

W. Wei, C. Liu, D. Yang, J. Wen, J. You, Y. Suo and H. Wang, Chem. Commun., 2013, 49, 10239 DOI: 10.1039/C3CC45803B

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