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Issue 77, 2013
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Voltammetric and spectroscopic characterization of early intermediates in the Co(ii)–polypyridyl-catalyzed reduction of water

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Abstract

Early intermediates of catalytic water reduction by a Co(II)–polypyridyl species have been characterized. Electrochemical detection of the Co(III)-hydride and time-resolved spectroscopic detection of the Co(I)-ligand intermediates provide an understanding of their reactivity in electrolytic or light-driven reduction of protons to hydrogen.

Graphical abstract: Voltammetric and spectroscopic characterization of early intermediates in the Co(ii)–polypyridyl-catalyzed reduction of water

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Publication details

The article was received on 21 Jun 2013, accepted on 17 Jul 2013 and first published on 22 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC44655G
Chem. Commun., 2013,49, 8638-8640

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    Voltammetric and spectroscopic characterization of early intermediates in the Co(II)–polypyridyl-catalyzed reduction of water

    W. M. Singh, M. Mirmohades, R. T. Jane, T. A. White, L. Hammarström, A. Thapper, R. Lomoth and S. Ott, Chem. Commun., 2013, 49, 8638
    DOI: 10.1039/C3CC44655G

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