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Issue 73, 2013
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Hydrogen-bond mediated regio- and enantioselectivity in a C–H amination reaction catalysed by a supramolecular Rh(ii) complex

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Abstract

Enantioselective (up to 74% ee) and regioselective C–H amination reactions of 3-benzylquinolones were achieved with a chiral C2-symmetric Rh(II) complex exhibiting two lactam binding sites for substrate coordination via hydrogen bonds.

Graphical abstract: Hydrogen-bond mediated regio- and enantioselectivity in a C–H amination reaction catalysed by a supramolecular Rh(ii) complex

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Article information


Submitted
04 Jun 2013
Accepted
09 Jul 2013
First published
05 Aug 2013

Chem. Commun., 2013,49, 8009-8011
Article type
Communication

Hydrogen-bond mediated regio- and enantioselectivity in a C–H amination reaction catalysed by a supramolecular Rh(II) complex

T. Höke, E. Herdtweck and T. Bach, Chem. Commun., 2013, 49, 8009
DOI: 10.1039/C3CC44197K

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