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Abstract | Cited by

Enantioselective (up to 74% ee) and regioselective C–H amination reactions of 3-benzylquinolones were achieved with a chiral C2-symmetric Rh(II) complex exhibiting two lactam binding sites for substrate coordination via hydrogen bonds.

Graphical abstract: Hydrogen-bond mediated regio- and enantioselectivity in a C–H amination reaction catalysed by a supramolecular Rh(ii) complex

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