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Issue 69, 2013
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Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity

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Abstract

A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N2 and CH4 gases.

Graphical abstract: Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity

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Article information


Submitted
26 Mar 2013
Accepted
28 Jun 2013
First published
28 Jun 2013

Chem. Commun., 2013,49, 7599-7601
Article type
Communication

Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity

S. S. Mondal, A. Bhunia, I. A. Baburin, C. Jäger, A. Kelling, U. Schilde, G. Seifert, C. Janiak and H. Holdt, Chem. Commun., 2013, 49, 7599
DOI: 10.1039/C3CC42156B

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