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Issue 34, 2013
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Multielectron transfer in a dicopper(ii) anthraquinophane†

María Castellano,a   Rafael Ruiz-García,ab   Joan Cano,*ab   Miguel Julve,a   Francesc Lloret,a   Yves Journaux,c   Giovanni De Munnod  and  Donatella Armentano*d  
Author affiliations

* Corresponding authors

a Instituto de Ciencia Molecular (ICMol), Universitat de València, 46980 Paterna, València, Spain
E-mail: joan.cano@uv.es

b Fundació General de la Universitat de València (FGUV), Universitat de València, 46980 Paterna, València, Spain

c Institut Parisien de Chimie Moléculaire, UPMC Univ Paris 06, UMR 7071, 75005 Paris, France

d Centro di Eccellenza CEMIF.CAL, Dipartimento di Chimica, Università della Calabria, 87030 Cosenza, Italy
E-mail: donatella.armentano@unical.it

Abstract

The new dinuclear copper(II) metallacyclophane with the non-innocent N,N′-1,4-bis(oxamate)-9,10-anthraquinone bridging ligand possesses a dual multielectron redox behavior featuring stepwise one-electron oxidation of the antiferromagnetically coupled CuII ions and two-electron reduction of the anthraquinone spacers in a π-stacked anti conformation.

Graphical abstract: Multielectron transfer in a dicopper(ii) anthraquinophane

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Article information

https://doi.org/10.1039/C3CC41434E
Submitted
25 Feb 2013
Accepted
11 Mar 2013
First published
13 Mar 2013
Chem. Commun., 2013,49, 3534-3536
Article type
Communication
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Multielectron transfer in a dicopper(II) anthraquinophane

M. Castellano, R. Ruiz-García, J. Cano, M. Julve, F. Lloret, Y. Journaux, G. De Munno and D. Armentano, Chem. Commun., 2013, 49, 3534
DOI: 10.1039/C3CC41434E

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