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Issue 34, 2013
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Multielectron transfer in a dicopper(ii) anthraquinophane

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Abstract

The new dinuclear copper(II) metallacyclophane with the non-innocent N,N′-1,4-bis(oxamate)-9,10-anthraquinone bridging ligand possesses a dual multielectron redox behavior featuring stepwise one-electron oxidation of the antiferromagnetically coupled CuII ions and two-electron reduction of the anthraquinone spacers in a π-stacked anti conformation.

Graphical abstract: Multielectron transfer in a dicopper(ii) anthraquinophane

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Article information


Submitted
25 Feb 2013
Accepted
11 Mar 2013
First published
13 Mar 2013

Chem. Commun., 2013,49, 3534-3536
Article type
Communication

Multielectron transfer in a dicopper(II) anthraquinophane

M. Castellano, R. Ruiz-García, J. Cano, M. Julve, F. Lloret, Y. Journaux, G. De Munno and D. Armentano, Chem. Commun., 2013, 49, 3534
DOI: 10.1039/C3CC41434E

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