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Abstract | Cited by

The new dinuclear copper(II) metallacyclophane with the non-innocent N,N′-1,4-bis(oxamate)-9,10-anthraquinone bridging ligand possesses a dual multielectron redox behavior featuring stepwise one-electron oxidation of the antiferromagnetically coupled CuII ions and two-electron reduction of the anthraquinone spacers in a π-stacked anti conformation.

Graphical abstract: Multielectron transfer in a dicopper(ii) anthraquinophane

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