Issue 37, 2013
From the journal:

Chemical Communications

Cucurbit[7]uril as a “protective agent”: controlling photochemistry and detecting 1-adamantanamine†

Hui Yang,a   Yiliu Liu,a   Liulin Yang,a   Kai Liu,a   Zhiqiang Wanga  and  Xi Zhang*a  

* Corresponding authors

a Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China
E-mail: xi@mail.tsinghua.edu.cn
Fax: +86-10-6277-1149
Tel: +86-10-6279-6283

Abstract

Cucurbit[7]uril (CB[7]) as a “protective agent” can effectively inhibit the [4+4] photochemical reaction of 1,1′-(butane-1,4-diyl)bis(2-aminopyridine)bromide (DPAD) by host–guest interaction between CB[7] and DPAD. In addition, the host–guest complex DPAD–CB[7] as a supramolecular sensor can detect the concentration of 1-adamantanamine with good sensitivity and selectivity because of the guest competitive complexation.

Graphical abstract: Cucurbit[7]uril as a “protective agent”: controlling photochemistry and detecting 1-adamantanamine

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Article information

DOI
https://doi.org/10.1039/C3CC41429A
Article type
Communication
Submitted
25 Feb 2013
Accepted
22 Mar 2013
First published
22 Mar 2013

Chem. Commun., 2013,49, 3905-3907

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Cucurbit[7]uril as a “protective agent”: controlling photochemistry and detecting 1-adamantanamine

H. Yang, Y. Liu, L. Yang, K. Liu, Z. Wang and X. Zhang, Chem. Commun., 2013, 49, 3905 DOI: 10.1039/C3CC41429A

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