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Issue 25, 2013
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Study of boron–nitrogen dative bonds using azetidine inversion dynamics

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Abstract

A method for probing the strength of B–N dative bonds is reported. The activation parameters for nitrogen inversion in a series of azetidines tethered to boronate esters have been quantified by VT-NMR and the measured barriers correlated with data obtained by 11B NMR, X-ray crystallography and MP2 calculations.

Graphical abstract: Study of boron–nitrogen dative bonds using azetidine inversion dynamics

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Article information


Submitted
24 Aug 2012
Accepted
12 Feb 2013
First published
13 Feb 2013

Chem. Commun., 2013,49, 2509-2511
Article type
Communication

Study of boron–nitrogen dative bonds using azetidine inversion dynamics

C. T. Hoang, I. Prokes, G. J. Clarkson, M. J. Rowland, J. H. R. Tucker, M. Shipman and T. R. Walsh, Chem. Commun., 2013, 49, 2509 DOI: 10.1039/C3CC36159D

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