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Issue 95, 2013
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Chemo-, regio-, and stereoselective iron-catalysed hydroboration of alkenes and alkynes

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Abstract

The highly chemo-, regio-, and stereoselective synthesis of alkyl- and vinyl boronic esters with good functional group tolerance has been developed using in situ activation of a bench-stable iron(II) pre-catalyst and pinacolborane (16 examples, 45–95% yield, TOF up to 30 000 mol h−1). The first iron-catalysed alkene hydrogermylation is also reported.

Graphical abstract: Chemo-, regio-, and stereoselective iron-catalysed hydroboration of alkenes and alkynes

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Article information


Submitted
03 Sep 2013
Accepted
15 Oct 2013
First published
17 Oct 2013

This article is Open Access

Chem. Commun., 2013,49, 11230-11232
Article type
Communication

Chemo-, regio-, and stereoselective iron-catalysed hydroboration of alkenes and alkynes

M. D. Greenhalgh and S. P. Thomas, Chem. Commun., 2013, 49, 11230
DOI: 10.1039/C3CC46727A

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