Issue 90, 2013

A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(i) and stereoelectronic properties

Abstract

A novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the three metals are essentially disconnected.

Graphical abstract: A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(i) and stereoelectronic properties

Supplementary files

Article information

Article type
Communication
Submitted
12 Aug 2013
Accepted
18 Sep 2013
First published
19 Sep 2013

Chem. Commun., 2013,49, 10572-10574

A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic properties

C. Segarra, J. Linke, E. Mas-Marzá, D. Kuck and E. Peris, Chem. Commun., 2013, 49, 10572 DOI: 10.1039/C3CC46155F

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