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Issue 82, 2013
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An organocatalytic asymmetric sequential allylic alkylation–cyclization of Morita–Baylis–Hillman carbonates and 3-hydroxyoxindoles

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Abstract

The first organocatalytic asymmetric sequential allylic alkylation–cyclization of Morita–Baylis–Hillman carbonates and 3-hydroxyoxindoles has been developed to afford spirooxindoles bearing α-methylene-γ-butyrolactone motifs in 25–85% yield, 60–94% ee and up to >20 : 1 diastereoselectivity.

Graphical abstract: An organocatalytic asymmetric sequential allylic alkylation–cyclization of Morita–Baylis–Hillman carbonates and 3-hydroxyoxindoles

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Publication details

The article was received on 09 Jul 2013, accepted on 31 Jul 2013 and first published on 01 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC45139A
Chem. Commun., 2013,49, 9422-9424

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    An organocatalytic asymmetric sequential allylic alkylation–cyclization of Morita–Baylis–Hillman carbonates and 3-hydroxyoxindoles

    Q. Wang, L. Peng, F. Wang, M. Zhang, L. Jia, F. Tian, X. Xu and L. Wang, Chem. Commun., 2013, 49, 9422
    DOI: 10.1039/C3CC45139A

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