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Issue 47, 2013
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Enantioselective total synthesis of (+)-brazilin, (−)-brazilein and (+)-brazilide A

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Abstract

An enantioselective strategy for the synthesis of (+)-brazilin, (−)-brazilein and (+)-brazilide A has been developed. A Lewis acid mediated lactonization established the novel fused bis-lactone core of brazilide A and finalized the first total synthesis of (+)-brazilide A.

Graphical abstract: Enantioselective total synthesis of (+)-brazilin, (−)-brazilein and (+)-brazilide A

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Article information


Submitted
02 Apr 2013
Accepted
23 Apr 2013
First published
09 May 2013

Chem. Commun., 2013,49, 5405-5407
Article type
Communication

Enantioselective total synthesis of (+)-brazilin, (−)-brazilein and (+)-brazilide A

X. Wang, H. Zhang, X. Yang, J. Zhao and C. Pan, Chem. Commun., 2013, 49, 5405
DOI: 10.1039/C3CC42385A

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