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Issue 49, 2013
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Efficient epoxidation of olefins by H2O2 catalyzed by iron “helmet” phthalocyanines

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Abstract

High yields of epoxides were obtained in the oxidation of a large range of olefins using 1.2–2 equiv. of H2O2 in the presence of iron helmet phthalocyanines. The involvement of high-valent iron oxo species was evidenced using cryospray mass spectrometry.

Graphical abstract: Efficient epoxidation of olefins by H2O2 catalyzed by iron “helmet” phthalocyanines

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Article information


Submitted
29 Mar 2013
Accepted
29 Apr 2013
First published
01 May 2013

Chem. Commun., 2013,49, 5577-5579
Article type
Communication

Efficient epoxidation of olefins by H2O2 catalyzed by iron “helmet” phthalocyanines

I. Y. Skobelev, E. V. Kudrik, O. V. Zalomaeva, F. Albrieux, P. Afanasiev, O. A. Kholdeeva and A. B. Sorokin, Chem. Commun., 2013, 49, 5577
DOI: 10.1039/C3CC42301H

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