Issue 17, 2013
From the journal:

Chemical Communications

Cyclic (amino)(imino)carbene complexes by borylene transfer to isocyanides†

Holger Braunschweig,*a   Thomas Herbst,a   Krzysztof Radacki,a   Christopher W. Tatea  and  Alfredo Vargasa  

* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany
E-mail: h.braunschweig@mail.uni-wuerzburg.de
Fax: +49 931 31 84623
Tel: +49 931 31 85260

Abstract

Here we report the facile formation of boron-containing cyclic (amino)(imino)carbene complexes by reaction of a chromium borylene complex [(OC)5Cr[double bond, length as m-dash]B[double bond, length as m-dash]N(SiMe3)2] with isocyanides.

Graphical abstract: Cyclic (amino)(imino)carbene complexes by borylene transfer to isocyanides

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Article information

DOI
https://doi.org/10.1039/C3CC38379B
Article type
Communication
Submitted
21 Nov 2012
Accepted
11 Jan 2013
First published
11 Jan 2013

Chem. Commun., 2013,49, 1702-1704

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Cyclic (amino)(imino)carbene complexes by borylene transfer to isocyanides

H. Braunschweig, T. Herbst, K. Radacki, C. W. Tate and A. Vargas, Chem. Commun., 2013, 49, 1702 DOI: 10.1039/C3CC38379B

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