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Issue 26, 2013
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Activation of CO2 by phosphinoamide hafnium complexes

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Abstract

Hf–phosphinoamide cation complexes behave as metal-based frustrated Lewis pairs and bind one or two equivalent of CO2 and in as well can activate CO2 in a bimetallic fashion to give a pseudo-tetrahedral P2CO2 fragment linking two Hf centres.

Graphical abstract: Activation of CO2 by phosphinoamide hafnium complexes

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Supplementary files

Article information


Submitted
17 Nov 2012
Accepted
27 Jan 2013
First published
05 Feb 2013

Chem. Commun., 2013,49, 2610-2612
Article type
Communication

Activation of CO2 by phosphinoamide hafnium complexes

M. J. Sgro and D. W. Stephan, Chem. Commun., 2013, 49, 2610
DOI: 10.1039/C3CC38286A

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