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Issue 14, 2013
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Structural design principles for self-assembled coordination polygons and polyhedra

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Abstract

Strategies for the design of ligands that combine with metal ions to form high-symmetry coordination assemblies are reviewed. Evaluation of crystal structure evidence reveals that prior design approaches, based on the concept of complementary bonding vector angles, fail to predict the majority of known examples. After explaining the reasons for this failure, it is shown how an alternative approach, de novo structure-based design, provides a practical method that predicts a much wider range of component shapes encoded to direct the formation of such assemblies.

Graphical abstract: Structural design principles for self-assembled coordination polygons and polyhedra

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Article information


Submitted
25 Oct 2012
Accepted
06 Dec 2012
First published
20 Dec 2012

Chem. Commun., 2013,49, 1354-1379
Article type
Feature Article

Structural design principles for self-assembled coordination polygons and polyhedra

N. J. Young and B. P. Hay, Chem. Commun., 2013, 49, 1354
DOI: 10.1039/C2CC37776D

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