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Issue 4, 2013
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A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands

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Abstract

By the reaction of TBA4H4[γ-SiW10O36] (TBA = tetra-n-butylammonium) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag6]4+ cluster, TBA8[Ag6(γ-H2SiW10O36)2]·5H2O, could be synthesized, and the molecular structure was determined.

Graphical abstract: A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands

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Supplementary files

Article information


Submitted
18 Oct 2012
Accepted
15 Nov 2012
First published
16 Nov 2012

Chem. Commun., 2013,49, 376-378
Article type
Communication

A discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands

Y. Kikukawa, Y. Kuroda, K. Suzuki, M. Hibino, K. Yamaguchi and N. Mizuno, Chem. Commun., 2013, 49, 376
DOI: 10.1039/C2CC37591E

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