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Issue 3, 2013
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Crystal structure of a luminescent thiolated Ag nanocluster with an octahedral Ag64+ core

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Abstract

A yellow luminescent thiolate-protected Ag14(SC6H3F2)12(PPh3)8 cluster was synthesized and structurally characterized by single-crystal X-ray analysis. The cluster contains an octahedral Ag64+ unit encapsulated by eight cubically arranged [Ag+(SC6H3F2)2PPh3] tetrahedra that share one corner (i.e. SC6H3F2) between them.

Graphical abstract: Crystal structure of a luminescent thiolated Ag nanocluster with an octahedral Ag64+ core

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Article information


Submitted
08 Oct 2012
Accepted
14 Nov 2012
First published
15 Nov 2012

Chem. Commun., 2013,49, 300-302
Article type
Communication

Crystal structure of a luminescent thiolated Ag nanocluster with an octahedral Ag64+ core

H. Yang, J. Lei, B. Wu, Y. Wang, M. Zhou, A. Xia, L. Zheng and N. Zheng, Chem. Commun., 2013, 49, 300
DOI: 10.1039/C2CC37347E

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