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Issue 40, 2012
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An investigation into thiol–ene surface chemistry of poly(ethylene glycol) acrylates, methacrylates and CCTP polymersviaquartz crystal microbalance with dissipation monitoring (QCM-D)

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Abstract

Thiol–ene reactions at surfaces have been investigated, comparing poly(ethylene glycol) (PEG) acrylate and methacrylate monomers with polymers made by cobalt catalysed chain transfer polymerisation (CCTP) using QCM-D. Thiolated surfaces were generated on silicon dioxide QCM-D sensors, with PEG monomers and polymers subsequently passed over the thiolated surface to study the thiol–ene reaction in the absence and presence of tris(2-carboxyethyl)phosphine, TCEP as catalyst.

Graphical abstract: An investigation into thiol–ene surface chemistry of poly(ethylene glycol) acrylates, methacrylates and CCTP polymers via quartz crystal microbalance with dissipation monitoring (QCM-D)

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Supplementary files

Article information


Submitted
06 Jun 2012
Accepted
01 Aug 2012
First published
28 Aug 2012

Soft Matter, 2012,8, 10388-10393
Article type
Paper

An investigation into thiol–ene surface chemistry of poly(ethylene glycol) acrylates, methacrylates and CCTP polymers via quartz crystal microbalance with dissipation monitoring (QCM-D)

S. Slavin and D. M. Haddleton, Soft Matter, 2012, 8, 10388 DOI: 10.1039/C2SM26304A

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