Cobalt analogs of Ru-based water oxidation catalysts: overcoming thermodynamic instability and kinetic lability to achieve electrocatalytic O2 evolution†
Abstract
Several binuclear cobalt(III) complexes that mimic Ru-based water oxidation
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* Corresponding authors
a
Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, USA
E-mail:
stahl@chem.wisc.edu
Fax: +1-608-262-6143
Tel: +1-608-265-6288
b Department of Bioinspired Science, Ewha Womans University, 120-750 Seoul, Korea
c
Institute of Chemical Research of Catalonia (ICIQ), Avinguda Països Catalans 16, E-43007 Tarragona, Spain
E-mail:
allobet@iciq.es
Several binuclear cobalt(III) complexes that mimic Ru-based water oxidation
M. L. Rigsby, S. Mandal, W. Nam, L. C. Spencer, A. Llobet and S. S. Stahl, Chem. Sci., 2012, 3, 3058 DOI: 10.1039/C2SC20755A
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