Issue 12, 2012

Methane: a new frontier in organometallic chemistry

Abstract

The base hydrocarbon of natural gas, methane, is one of the most unreactive hydrocarbons in terms of C–H bond dissociation enthalpy, ionization potential, and pKa. A perspective on the C–H activation of this potent greenhouse gas, by homogeneous and well-defined organometallic complexes is presented, with an emphasis on several recent advances in this field.

Graphical abstract: Methane: a new frontier in organometallic chemistry

Article information

Article type
Minireview
Submitted
27 Apr 2012
Accepted
06 Jul 2012
First published
06 Jul 2012

Chem. Sci., 2012,3, 3356-3365

Methane: a new frontier in organometallic chemistry

V. N. Cavaliere and D. J. Mindiola, Chem. Sci., 2012, 3, 3356 DOI: 10.1039/C2SC20530K

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