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Issue 4, 2012
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Joint electrical, photophysical and computational studies on D-π-A dye sensitized solar cells: the impacts of dithiophene rigidification

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Abstract

The rigidification of π-conjugated segments represents a feasible tactic towards energy-level engineering of organic D-π-A dyes in mesoscopic titania solar cells. In this work, comparions of four dyes with the di(3-hexylthiophene), dihexyldithienosilole, dihexylcyclopentadithiophene and N-hexyldithienopyrrole linkers have revealed some general influences of π-linker rigidification on the optoelectronic features of titania solar cells employing a cobalt(II/III) redox electrolyte, in terms of energetic and kinetic viewpoints. Compared to a dye with the di(3-hexylthiophene) linker, its three counterparts with rigidified dithiophene blocks present bathochromic and hyperchromic absorptions of solar photons. Transient absorption measurements have shown that the incorporation of Si-, C- and N-bridged dithiophene segments decelerates the dye regeneration kinetics. The rigidification of π-conjugated dithiophene linkers brings forth a general open-circuit photovoltage diminishment, in the range from 60 to 190 mV. Further insightful impedance analyses have disclosed that the open-circuit photovoltage reduction, due to the π-linker alternation from di(3-hexylthiophene) to N-hexyldithienopyrrole, is predominantly caused by an adverse downward displacement of the titania conduction band edge, despite a positive contribution from attenuated charge recombination at the titania/electrolyte interface.

Graphical abstract: Joint electrical, photophysical and computational studies on D-π-A dye sensitized solar cells: the impacts of dithiophene rigidification

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Supplementary files

Article information


Submitted
25 Nov 2011
Accepted
19 Dec 2011
First published
20 Dec 2011

Chem. Sci., 2012,3, 976-983
Article type
Edge Article

Joint electrical, photophysical and computational studies on D-π-A dye sensitized solar cells: the impacts of dithiophene rigidification

M. Xu, M. Zhang, M. Pastore, R. Li, F. De Angelis and P. Wang, Chem. Sci., 2012, 3, 976
DOI: 10.1039/C2SC00973K

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