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Issue 2, 2012
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Preparation of cationic cobaltoceniumpolymers and block copolymers by “living” ring-opening metathesispolymerization

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Abstract

We report a robust synthetic strategy to prepare high molecular weight side-chain cationic cobaltocenium-containing polymers and block copolymers via ring-opening metathesis polymerization. All polymerizations were extremely fast with high yields (∼100%) under open air conditions at room temperature and followed a living and controlled manner.

Graphical abstract: Preparation of cationic cobaltocenium polymers and block copolymers by “living” ring-opening metathesis polymerization

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Article information


Submitted
11 Oct 2011
Accepted
09 Nov 2011
First published
10 Nov 2011

Chem. Sci., 2012,3, 580-583
Article type
Edge Article

Preparation of cationic cobaltocenium polymers and block copolymers by “living” ring-opening metathesis polymerization

L. Ren, J. Zhang, X. Bai, C. G. Hardy, K. D. Shimizu and C. Tang, Chem. Sci., 2012, 3, 580
DOI: 10.1039/C1SC00783A

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