Issue 30, 2012
From the journal:

RSC Advances

Microporous metal–organic framework containing cages with adjustable portal dimensions for adsorptive CO2 separation†

Jung Hee Yoon,a   Dongwook Kim,a   Xiaokai Song,ab   Seungwan Han,a   Jiho Shin,c   Suk Bong Hong*c  and  Myoung Soo Lah*a  

* Corresponding authors

a Interdisciplinary School of Green Energy, Ulsan National Institute of Science & Technology, Ulsan, Korea
E-mail: mslah@unist.ac.kr
Fax: +82 52 217 2019
Tel: +82 52 217 2931

b Department of Chemistry and Applied Chemistry, Hanyang University, Ansan, Kyunggi-do, Korea

c Department of Chemical Engineering and School of Environmental Science and Engineering, POSTECH, Pohang, Korea

Abstract

The excellent breakthrough separation performance of a new microporous MOF for CO2/N2 and CO2/CH4 gas mixtures results from the combination of different equilibrium uptake amounts depending on the adsorption enthalpies of the adsorbates and different uptake kinetics depending on their kinetic diameters.

Graphical abstract: Microporous metal–organic framework containing cages with adjustable portal dimensions for adsorptive CO2 separation

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Article information

DOI
https://doi.org/10.1039/C2RA22118G
Article type
Paper
Submitted
11 Sep 2012
Accepted
27 Sep 2012
First published
19 Oct 2012

RSC Adv., 2012,2, 11566-11573

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Microporous metal–organic framework containing cages with adjustable portal dimensions for adsorptive CO2 separation

J. H. Yoon, D. Kim, X. Song, S. Han, J. Shin, S. B. Hong and M. S. Lah, RSC Adv., 2012, 2, 11566 DOI: 10.1039/C2RA22118G

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