Issue 12, 2012
From the journal:

RSC Advances

Brownian dynamics determine universality of charge transport in ionic liquids

J. R. Sangoro,ac   M. Mierzwa,b   C. Iacob,a   M. Paluchb  and  F. Kremera  

a Institute of Experimental Physics I, University of Leipzig, Linnéstr. 5, Leipzig, Germany
E-mail: sangorojr@ornl.gov, sangoro@physik.uni-leipzig.de

b Silesian University, Katowice, Poland

c Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, USA

Abstract

Broadband dielectric spectroscopy is employed to investigate charge transport in a variety of glass-forming ionic liquids over wide frequency, temperature and pressure ranges. Using a combination of Einstein, Einstein-Smoluchowski, and Langevin relations, the observed universal scaling of charge transport in ionic liquids is traced back to the dominant role of Brownian dynamics.

Graphical abstract: Brownian dynamics determine universality of charge transport in ionic liquids

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Article information

DOI
https://doi.org/10.1039/C2RA20560B
Article type
Communication
Submitted
27 Mar 2012
Accepted
28 Mar 2012
First published
02 May 2012

RSC Adv., 2012,2, 5047-5050

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Brownian dynamics determine universality of charge transport in ionic liquids

J. R. Sangoro, M. Mierzwa, C. Iacob, M. Paluch and F. Kremer, RSC Adv., 2012, 2, 5047 DOI: 10.1039/C2RA20560B

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