A hexa(choloyl) conjugate bearing a rigid p-phenylenediamine linker was synthesized and shown to produce dimer-based pores in POPC bilayers. This is in sharp contrast to a previous finding that its octa(choloyl) analog formed monomer-based pores, and supplies a fine line between unimolecular and bimolecular pores formed from poly(choloyl) conjugates of this type.
W. Chen, RSC Adv., 2012, 2, 6389 DOI: 10.1039/C2RA20121F
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