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Issue 15, 2012
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Ruthenium catalysed one-pot synthesis of S-allyl and cinnamyl dithiocarbamates using allyl and cinnamyl acetates in water

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Abstract

A convenient and efficient procedure for the synthesis of S-allyl/cinnamyl dithiocarbamates has been developed by a one-pot reaction of allyl/cinnamyl acetate, carbon disulfide and amine in presence of Ru(acac)3 in water. A variety of functionalized dithiocarbamates have been obtained by this procedure in high yields. The reaction proceeds via a catalytic Ru(II) species, generated in situ during the reaction.

Graphical abstract: Ruthenium catalysed one-pot synthesis of S-allyl and cinnamyl dithiocarbamates using allyl and cinnamyl acetates in water

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Publication details

The article was received on 03 May 2012, accepted on 10 May 2012 and first published on 14 Jun 2012


Article type: Paper
DOI: 10.1039/C2RA20856C
RSC Adv., 2012,2, 6329-6335

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    Ruthenium catalysed one-pot synthesis of S-allyl and cinnamyl dithiocarbamates using allyl and cinnamyl acetates in water

    S. Ahammed, A. Saha and B. C. Ranu, RSC Adv., 2012, 2, 6329
    DOI: 10.1039/C2RA20856C

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