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Direct arylation polycondensation of a bithiazole derivative with dibromoarylenes gave the corresponding bithiazole-based copolymers using the phosphine-free catalytic system in a short reaction time.

Graphical abstract: Synthesis of 4,4′-dinonyl-2,2′-bithiazole-based copolymers via Pd-catalyzed direct C–H arylation

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