Aluminium triflate catalysed O-glycosidation: temperature-switched selective Ferrier rearrangement or direct addition with alcohols†
Abstract
A temperature-controlled mechanism switch between the Al(OTf)3-catalysed direct addition of
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* Corresponding authors
a
Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, P.O. Box 524, Auckland Park, South Africa
E-mail:
bwilliams@uj.ac.za
Fax: +2711 559 2819
Tel: +2711 559 3431
b
Industrial Research Limited, 69 Gracefield Road, Lower Hutt, New Zealand
E-mail:
b.williams@irl.cri.nz
Fax: +644 566 6004
Tel: +644 931 3421
A temperature-controlled mechanism switch between the Al(OTf)3-catalysed direct addition of
D. B. G. Williams, S. B. Simelane and H. H. Kinfe, Org. Biomol. Chem., 2012, 10, 5636 DOI: 10.1039/C2OB25540E
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