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Issue 14, 2012
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Ag44(SR)304−: a silver–thiolate superatom complex

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Abstract

Intensely and broadly absorbing nanoparticles (IBANs) of silver protected by arylthiolates were recently synthesized and showed unique optical properties, yet question of their dispersity and their molecular formulas remained. Here IBANs are identified as a superatom complex with a molecular formula of Ag44(SR)304− and an electron count of 18. This molecular character is shared by IBANs protected by 4-fluorothiophenol or 2-naphthalenethiol. The molecular formula and purity is determined by mass spectrometry and confirmed by sedimentation velocity-analytical ultracentrifugation. The data also give preliminary indications of a unique structure and environment for Ag44(SR)304−.

Graphical abstract: Ag44(SR)304−: a silver–thiolate superatom complex

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Article information


Submitted
31 Mar 2012
Accepted
04 Jun 2012
First published
15 Jun 2012

Nanoscale, 2012,4, 4269-4274
Article type
Paper

Ag44(SR)304−: a silver–thiolate superatom complex

K. M. Harkness, Y. Tang, A. Dass, J. Pan, N. Kothalawala, V. J. Reddy, D. E. Cliffel, B. Demeler, F. Stellacci, O. M. Bakr and J. A. McLean, Nanoscale, 2012, 4, 4269
DOI: 10.1039/C2NR30773A

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