Issue 20, 2012
From the journal:

Journal of Materials Chemistry

MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application†

Felix Jeremias,ab   Anupam Khutia,b   Stefan K. Henninger*a  and  Christoph Janiak*b  

* Corresponding authors

a Dept. Thermally Active Materials and Solar Cooling, Fraunhofer Institute for Solar Energy Systems ISE, Heidenhofstr. 2, Freiburg, Germany
E-mail: stefan.henninger@ise.fraunhofer.de
Fax: +49 761 4588 9000
Tel: +49 761 4588 5104

b Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, Düsseldorf, Germany
E-mail: janiak@uni-duesseldorf.de
Fax: +49 211 8112287

Abstract

The adsorption/desorption of up to 0.75 g of water vapour per g of the porous MOFs 3D-{M3O(X)(H2O)2[btc]2·nH2O}, MIL-100 (M = Al, Fe; X = OH, F, btc = benzene-1,3,5-tricarboxylate, trimesate), occurs at small relative pressures of p/p0 < 0.4 and a comparatively small hysteresis. Together with very good cycle stability, these properties render both MIL-100(Al and Fe) very suitable candidates for thermally driven heat pumps or adsorption chillers.

Graphical abstract: MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application

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Article information

DOI
https://doi.org/10.1039/C2JM15615F
Article type
Communication
Submitted
02 Nov 2011
Accepted
12 Dec 2011
First published
23 Dec 2011

J. Mater. Chem., 2012,22, 10148-10151

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MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application

F. Jeremias, A. Khutia, S. K. Henninger and C. Janiak, J. Mater. Chem., 2012, 22, 10148 DOI: 10.1039/C2JM15615F

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