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Issue 20, 2012
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MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application

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Abstract

The adsorption/desorption of up to 0.75 g of water vapour per g of the porous MOFs 3D-{M3O(X)(H2O)2[btc]2·nH2O}, MIL-100 (M = Al, Fe; X = OH, F, btc = benzene-1,3,5-tricarboxylate, trimesate), occurs at small relative pressures of p/p0 < 0.4 and a comparatively small hysteresis. Together with very good cycle stability, these properties render both MIL-100(Al and Fe) very suitable candidates for thermally driven heat pumps or adsorption chillers.

Graphical abstract: MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application

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Publication details

The article was received on 02 Nov 2011, accepted on 12 Dec 2011 and first published on 23 Dec 2011


Article type: Communication
DOI: 10.1039/C2JM15615F
Citation: J. Mater. Chem., 2012,22, 10148-10151
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    MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application

    F. Jeremias, A. Khutia, S. K. Henninger and C. Janiak, J. Mater. Chem., 2012, 22, 10148
    DOI: 10.1039/C2JM15615F

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