Issue 20, 2012
From the journal:

Journal of Materials Chemistry

A robust microporous metal–organic framework constructed from a flexible organic linker for highly selective sorption of methanol over ethanol and water†

Qian Huang,a   Jianfeng Cai,a   Hui Wu,cd   Yabing He,b   Banglin Chen*ab  and  Guodong Qian*a  

* Corresponding authors

a State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China
E-mail: gdqian@zju.edu.cn

b Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA
E-mail: banglin.chen@utsa.edu
Fax: (+1) 210-458-7428

c NIST Center for Neutron Research, Gaithersburg, Maryland 20899-6102, USA

d Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742, USA

Abstract

A microporous metal–organic framework MOF 1 [Zn(L)2(methanol)2] (H2L = (1R,3S)-1,2,2-trimethyl-3-(pyridin-4-ylcarbamoyl)cyclopentanecarboxylic acid) constructed from a flexible Zn2+ node and a flexible organic linker L was obtained by solvothermal reaction of diamond topology, and exhibits highly selective sorption of methanol over ethanol and water.

Graphical abstract: A robust microporous metal–organic framework constructed from a flexible organic linker for highly selective sorption of methanol over ethanol and water

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Article information

DOI
https://doi.org/10.1039/C2JM15604K
Article type
Paper
Submitted
02 Nov 2011
Accepted
30 Mar 2012
First published
17 Apr 2012

J. Mater. Chem., 2012,22, 10352-10355

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A robust microporous metal–organic framework constructed from a flexible organic linker for highly selective sorption of methanol over ethanol and water

Q. Huang, J. Cai, H. Wu, Y. He, B. Chen and G. Qian, J. Mater. Chem., 2012, 22, 10352 DOI: 10.1039/C2JM15604K

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