Issue 12, 2012
From the journal:

Green Chemistry

Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions†

Yalei Zhang,*ab   Zheng Shen,*abc   Xuefei Zhou,ab   Min Zhangb  and  Fangmin Jin*a  

* Corresponding authors

a State Key Laboratory of Pollution Control and Resources Reuse, Key Laboratory of Yangtze River Water Environment of MOE, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China
E-mail: zhangyalei@tongji.edu.cn, fmjin@tongji.edu.cn

b National Engineering Research Center of Facilities Agriculture, Institute of Modern Agricultural Science & Engineering, Tongji University, Shanghai 200092, China
E-mail: 78shenzheng@tongji.edu.cn

c State Key Laboratory of Catalysis Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Abstract

To discover the reaction mechanism for the production of hydrogen and lactic acid from glycerol under alkaline hydrothermal conditions, we identified the different intermediates involved during reactions by investigating the solvent isotope effect with 1H-NMR, 2H-NMR, LC-MS and Gas-MS analyses, and then proposed and proved a potential reaction mechanism.

Graphical abstract: Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions

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Article information

DOI
https://doi.org/10.1039/C2GC36153A
Article type
Communication
Submitted
24 Jul 2012
Accepted
02 Oct 2012
First published
02 Oct 2012

Green Chem., 2012,14, 3285-3288

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Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions

Y. Zhang, Z. Shen, X. Zhou, M. Zhang and F. Jin, Green Chem., 2012, 14, 3285 DOI: 10.1039/C2GC36153A

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