A one-pot approach for conversion of fructose to 2,5-diformylfuran by combination of Fe3O4-SBA-SO3H and K-OMS-2

Zhen-Zhen Yang; Jin Deng; Tao Pan; Qing-Xiang Guo; Yao Fu

doi:10.1039/C2GC35947B

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A one-pot approach for conversion of fructose to 2,5-diformylfuran by combination of Fe₃O₄-SBA-SO₃H and K-OMS-2†

Zhen-Zhen Yang,^a Jin Deng,^a Tao Pan,^a Qing-Xiang Guo^a and Yao Fu*^a

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* Corresponding authors

^a Anhui Province Key Laboratory of Biomass Clean Energy, Department of Chemistry, University of Science and Technology of China, Hefei 230026, P.R. China
E-mail: fuyao@ustc.edu.cn
Fax: (+86) 551-360-6689

Abstract

We have demonstrated an efficient, selective and environmentally benign heterogeneous catalyst (K-OMS-2) for aerobic oxidation of 5-HMF to 2,5-DFF. In addition, a combination of Fe₃O₄-SBA-SO₃H and K-OMS-2 successfully catalyzed direct synthesis of 2,5-DFF from fructose via acid-catalyzed dehydration and successive aerobic oxidation in one-pot reaction.

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Article information

DOI: https://doi.org/10.1039/C2GC35947B
Article type: Communication
Submitted: 21 Jun 2012
Accepted: 28 Aug 2012
First published: 29 Aug 2012

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Green Chem., 2012,14, 2986-2989

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A one-pot approach for conversion of fructose to 2,5-diformylfuran by combination of Fe₃O₄-SBA-SO₃H and K-OMS-2

Z. Yang, J. Deng, T. Pan, Q. Guo and Y. Fu, Green Chem., 2012, 14, 2986 DOI: 10.1039/C2GC35947B

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