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Issue 10, 2012
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Towards the development of a hydrogen battery

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Abstract

A novel Ru-catalyzed hydrogenation of carbon dioxide proceeds with an unprecedented high formic acid to amine ratio (AAR of 2.69), which results in an improved energy content. The presented catalyst system allows for reversible fast hydrogen loading (even at RT) and unprecedented unloading (TON for H2 liberation of 800 000).

Graphical abstract: Towards the development of a hydrogen battery

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Article information


Submitted
25 Apr 2012
Accepted
11 Jul 2012
First published
12 Jul 2012

Energy Environ. Sci., 2012,5, 8907-8911
Article type
Communication

Towards the development of a hydrogen battery

A. Boddien, C. Federsel, P. Sponholz, D. Mellmann, R. Jackstell, H. Junge, G. Laurenczy and M. Beller, Energy Environ. Sci., 2012, 5, 8907
DOI: 10.1039/C2EE22043A

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