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Issue 33, 2013
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Vanadium-catalyzed enantioselective Friedel–Crafts-type reactions

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Abstract

Vanadium-mediated enantioselective Friedel–Crafts (FC)-type reactions were established using the dinuclear vanadium complex (Ra,S,S)-1a. The vanadium complex promoted the FC-type reaction of imines with 2-naphthols or indoles to give corresponding adducts with high enantioselectivities.

Graphical abstract: Vanadium-catalyzed enantioselective Friedel–Crafts-type reactions

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Article information


Submitted
21 Sep 2012
Accepted
08 Oct 2012
First published
10 Oct 2012

Dalton Trans., 2013,42, 11787-11790
Article type
Communication

Vanadium-catalyzed enantioselective Friedel–Crafts-type reactions

S. Takizawa, F. A. Arteaga, Y. Yoshida, J. Kodera, Y. Nagata and H. Sasai, Dalton Trans., 2013, 42, 11787
DOI: 10.1039/C2DT32202A

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