Issue 46, 2012
From the journal:

Dalton Transactions

Three novel 3D coordination polymers based on a flexible multisite cyclotetraphosphazene ligand†

Xingjun Li,ab   Feilong Jiang,a   Lian Chen,a   Mingyan Wu,a   Qihui Chen,a   Yang Buab  and  Maochun Hong*a  

* Corresponding authors

a State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: hmc@fjirsm.ac.cn
Fax: +86-591-83794946
Tel: +86-591-83714605

b Graduate School of the Chinese Academy of Sciences, Beijing, China

Abstract

A novel flexible multisite cyclotetraphosphazene ligand, octakis(4-pyridylamino)cyclotetraphosphazene (OPCP), was synthesized through a new method, and it represents the first fully substituted pyridylaminocylcophosphazene ligand with eight coordinating arms. Self-assemblies of OPCP and different transition metal ions result in three novel 3D coordination polymers, in which the Cd(II) complex exhibits a quite strong blue emission.

Graphical abstract: Three novel 3D coordination polymers based on a flexible multisite cyclotetraphosphazene ligand

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Article information

DOI
https://doi.org/10.1039/C2DT31852K
Article type
Communication
Submitted
14 Aug 2012
Accepted
28 Sep 2012
First published
04 Oct 2012

Dalton Trans., 2012,41, 14038-14041

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Three novel 3D coordination polymers based on a flexible multisite cyclotetraphosphazene ligand

X. Li, F. Jiang, L. Chen, M. Wu, Q. Chen, Y. Bu and M. Hong, Dalton Trans., 2012, 41, 14038 DOI: 10.1039/C2DT31852K

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