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Issue 39, 2012
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Incorporation of spin-5/2 chain into 2D network with conformational pure e,a-cis-cyclohexane-1,4-dicarboxylato linker

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Abstract

A two-dimensional coordination network, 2[FeIII (OH)(e,a-cis-1,4-chdc)] (1,4-chdc: cyclohexane-1,4-dicarboxylate), featuring one-dimensional iron(III)-hydroxy chains that are transversely bridged by 1,4-chdc in its pure e,a-cis conformation have been isolated. The magnetic study shows a typical spin-5/2 Heisenberg chain above 20 K, but canted antiferromagnetic ordering at lower temperatures.

Graphical abstract: Incorporation of spin-5/2 chain into 2D network with conformational pure e,a-cis-cyclohexane-1,4-dicarboxylato linker

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Publication details

The article was received on 19 Jul 2012, accepted on 16 Aug 2012 and first published on 20 Aug 2012


Article type: Communication
DOI: 10.1039/C2DT31613G
Citation: Dalton Trans., 2012,41, 11989-11991

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    Incorporation of spin-5/2 chain into 2D network with conformational pure e,a-cis-cyclohexane-1,4-dicarboxylato linker

    Y. Zheng and X. Chen, Dalton Trans., 2012, 41, 11989
    DOI: 10.1039/C2DT31613G

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