Issue 25, 2012
From the journal:

Dalton Transactions

Hydroformylation by Pt–Sn compounds from N-heterocyclic stannylenes†

Benjamin M. Day,a   Philip W. Dyerb  and  Martyn P. Coles*c  

* Corresponding authors

a Department of Chemistry, University of Sussex, Falmer, Brighton BN1 9QJ, UK

b Centre for Sustainable Process Chemistry, Department of Chemistry, Durham University, South Road, Durham DH1 3LE, UK

c School of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington 6140, New Zealand
E-mail: martyn.coles@vuw.ac.nz
Fax: +64 (0)4 463 5241
Tel: +64 (0)4 463 6357

Abstract

[(Me2Si{NAr}2)-κ2N,N′]Sn, reacts with PtCl2(L2) and [PtCl(μ-Cl)(L)]2 to afford products containing Pt–Sn bonds. In the absence of supporting ligands L, coordination of the stannylene and rearrangement to a structurally unique PtSn2N2Si metallacycle occurs. The hydroformylation activity of a representative Pt–Sn compound is investigated.

Graphical abstract: Hydroformylation by Pt–Sn compounds from N-heterocyclic stannylenes

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Article information

DOI
https://doi.org/10.1039/C2DT30988B
Article type
Communication
Submitted
18 Apr 2012
Accepted
10 May 2012
First published
10 May 2012

Dalton Trans., 2012,41, 7457-7460

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Hydroformylation by Pt–Sn compounds from N-heterocyclic stannylenes

B. M. Day, P. W. Dyer and M. P. Coles, Dalton Trans., 2012, 41, 7457 DOI: 10.1039/C2DT30988B

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