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Issue 37, 2012
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Novel heterostructured Bi2S3/BiOI photocatalyst: facile preparation, characterization and visible light photocatalytic performance

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Abstract

Novel Bi2S3/BiOI heterostructures were successfully synthesized through a facile and economical ion exchange method between BiOI and thioacetamide (CH3CSNH2), and characterized by multiform techniques, such as XRD, Raman, FT-IR, XPS, SEM, TEM, HRTEM, SAED, BET and DRS. The obtained Bi2S3/BiOI photocatalysts showed excellent photocatalytic performance for decomposing organic dye methyl orange (MO) compared with pure BiOI under visible light irradiation (λ > 420 nm). Among the Bi2S3/BiOI photocatalysts with different molar percentage of Bi2S3 to initial BiOI (from 2 to 8%), 4% Bi2S3/BiOI exhibited the highest photocatalytic activity with apparent kapp of 0.2968 h−1. Differently, Bi2S3/BiOI displayed low photocatalytic activity for many colorless organic substrates, such as phenol, 2-chlorophenol, dimethyl phthalate and 5-sulfosalicylic acid. Moreover, the study on the mechanism suggested that the enhanced photocatalytic activity mainly resulted from the role of Bi2S3–BiOI heterojunctions formed in the Bi2S3/BiOI, which could lead to efficient separation of photoinduced carriers.

Graphical abstract: Novel heterostructured Bi2S3/BiOI photocatalyst: facile preparation, characterization and visible light photocatalytic performance

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Supplementary files

Article information


Submitted
21 Feb 2012
Accepted
16 Jul 2012
First published
17 Jul 2012

Dalton Trans., 2012,41, 11482-11490
Article type
Paper

Novel heterostructured Bi2S3/BiOI photocatalyst: facile preparation, characterization and visible light photocatalytic performance

J. Cao, B. Xu, H. Lin, B. Luo and S. Chen, Dalton Trans., 2012, 41, 11482
DOI: 10.1039/C2DT30883E

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